Understanding the Relationship Between Vapour Density and Relative Molecular Mass

Relationship Between Vapour Density and Relative Molecular Mass | 10th Science

Relationship Between Vapour Density and Relative Molecular Mass

10th Science | Chapter 7: Atoms and Molecules

RELATIONSHIP BETWEEN VAPOUR DENSITY AND RELATIVE MOLECULAR MASS

1. Relative molecular mass: (Hydrogen scale)

The Relative Molecular Mass of a gas or vapour is the ratio between the mass of one molecule of the gas or vapour to mass of one atom of Hydrogen.

2. Vapour Density:

Vapour density is the ratio of the mass of a certain volume of a gas or vapour, to the mass of an equal volume of hydrogen, measured under the same conditions of temperature and pressure.

Vapour Density (V.D.) =

Formula for Vapour Density

According to Avogadro's law, equal volumes of all gases contain equal number of molecules.

Thus, let the number of molecules in one volume = n, then

V.D. at S.T.P =

Vapour density at STP formula based on n molecules

Cancelling 'n' which is common, you get V.D.

Vapour density formula after cancelling n

When you compare the formula of vapour density with relative molecular mass, they can be represented as V.D.

Comparison of Vapour Density and Relative Molecular Mass formulas

You can therefore substitute the above equation to an Eqn 7.1 and arrive at the following formula

Substituting Relative Molecular Mass into Vapour Density formula

Now on cross multiplication, you have

2 × vapour density = Relative molecular mass of a gas

(Or)

Relative molecular mass = 2 × Vapour density